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Several research to explore the possible conversion of CO2 using rhenium(I) tricarbonyl complexes have been reported the last years. In the present work, we investigated a potential use of fac-Re(CO)3(4,4′-di-methyl-2,2′-bipyridyl)L+ complex (C2), where L is an electron-withdrawing ancillary liga...


Canales, J.C.Carreño, A.Oyarzún, D.Manríquez, J.M.Chávez, I.[A preliminary study on electrocatalytic reduction of CO2 using FAC-ReI(CO)3(4,4′-dimethyl-2,2′-bipyridyl)((E)-2-((3-amino-pyridin-4-ylimino)-methyl)-4,6-DI-tert-butylphenol))+ complex]A preliminary study on electrocatalytic reduction of CO2 using FAC-ReI(CO)3(4,4′-dimethyl-2,2′-bipyridyl)((E)-2-((3-amino-pyridin-4-ylimino)-methyl)-4,6-DI-tert-butylphenol))+ complex

This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these t...


Araneda, J.F.Salinas, S.Mac-Leod-Carey, D.Muñoz-Castro, A.Arratia-Perez, R.Adams, C.Chávez, I.Manríquez, J. M.[Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene]Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene

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