Different strategies to improve the excited state properties of polypyridinic complexes by varying ligand structure and molecular geometry are described. Bidentate and tetradentate ligands based on fragments as dipyrido[3,2-a:2′,3′-c]phenazine, dppz, and pyrazino[2,3-f][1,10]-phenanthroline, ppl,...
Arias, M.
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Concepción, J.
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Crivelli, I.
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Delgadillo, A.
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Díaz Harris, Ramiro
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Francois Cifuentes, María Angélica
,
Gajardo, F.
,
López, R.
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Leiva, A.M.
,
Loeb, B.
,
[Influence of ligand structure and molecular geometry on the properties of d6 polypyridinic transition metal complexes]
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Influence of ligand structure and molecular geometry on the properties of d6 polypyridinic transition metal complexes
A new acceptor polypyridinic ligand functionalized with a quinone fragment is reported. The ligand, dipyrido[3,2-a:2′,3′-c]-benzo[3,4]-phenazine-11,16-quinone, Nqphen, was synthesized by condensation of 1,10-phenanthroline-5,6-dione and 2,3-diamino-1,4-naphthoquinone. The syntheses of two rhenium...
Díaz Harris, Ramiro
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Reyes, O.
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Francois Cifuentes, María Angélica
,
Leiva, M.A.
,
Loeb, B.
,
[Synthesis of a new polypyridinic highly conjugated ligand with electron-acceptor properties]
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Synthesis of a new polypyridinic highly conjugated ligand with electron-acceptor properties
A series of tricarbonyl rhenium(I) complexes of the type fac-[Re 1(CO)3(Ppl)(L)]0/+, where ppl is pyrazino[2,3-f][1,10]phenanthroline, and where L is Cl-, TIO -, 4-(tert-butyl)pyridine (tBu-py), 4-methoxypyridine (MeO-py), 4,4′-bipyridyl (bpy), or 10-(picolin-4-yl)phenothiazine (pptz), were synth...
Díaz Harris, Ramiro
,
Francois Cifuentes, María Angélica
,
Leiva, A.M.
,
Loeb, B.
,
Norambuena, E.
,
Yañez, M.
,
[Synthesis and characterization of polypiridine-based rhenium(I) complexes with pyrazino[2,3-f][1,10]phenanthroline]
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Synthesis and characterization of polypiridine-based rhenium(I) complexes with pyrazino[2,3-f][1,10]phenanthroline