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Different strategies to improve the excited state properties of polypyridinic complexes by varying ligand structure and molecular geometry are described. Bidentate and tetradentate ligands based on fragments as dipyrido[3,2-a:2′,3′-c]phenazine, dppz, and pyrazino[2,3-f][1,10]-phenanthroline, ppl,...


Arias, M.Concepción, J.Crivelli, I.Delgadillo, A.Díaz Harris, RamiroFrancois Cifuentes, María AngélicaGajardo, F.López, R.Leiva, A.M.Loeb, B.[Influence of ligand structure and molecular geometry on the properties of d6 polypyridinic transition metal complexes]Influence of ligand structure and molecular geometry on the properties of d6 polypyridinic transition metal complexes

A new acceptor polypyridinic ligand functionalized with a quinone fragment is reported. The ligand, dipyrido[3,2-a:2′,3′-c]-benzo[3,4]-phenazine-11,16-quinone, Nqphen, was synthesized by condensation of 1,10-phenanthroline-5,6-dione and 2,3-diamino-1,4-naphthoquinone. The syntheses of two rhenium...


Díaz Harris, RamiroReyes, O.Francois Cifuentes, María AngélicaLeiva, M.A.Loeb, B.[Synthesis of a new polypyridinic highly conjugated ligand with electron-acceptor properties]Synthesis of a new polypyridinic highly conjugated ligand with electron-acceptor properties

A series of tricarbonyl rhenium(I) complexes of the type fac-[Re 1(CO)3(Ppl)(L)]0/+, where ppl is pyrazino[2,3-f][1,10]phenanthroline, and where L is Cl-, TIO -, 4-(tert-butyl)pyridine (tBu-py), 4-methoxypyridine (MeO-py), 4,4′-bipyridyl (bpy), or 10-(picolin-4-yl)phenothiazine (pptz), were synth...


Díaz Harris, RamiroFrancois Cifuentes, María AngélicaLeiva, A.M.Loeb, B.Norambuena, E.Yañez, M.[Synthesis and characterization of polypiridine-based rhenium(I) complexes with pyrazino[2,3-f][1,10]phenanthroline]Synthesis and characterization of polypiridine-based rhenium(I) complexes with pyrazino[2,3-f][1,10]phenanthroline

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